GC-PID method for the measurement of arsenic in food and juice

Coming to New Orleans, LA in April 2013: a two day symposium on Arsenic Contamination in Food and Water

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244th American Chemical Society National Meeting

Philadelphia, PA 

Monday Evening SCI-MIX 8/20/12  & Wednesday Evening 8/22/12

Document ID: 15727

Jack Driscoll and Greg Cutter 2011 aboard the RV/Knorr

Program Area: ENVR: Division of Environmental Chemistry   

Symposium Title: (ENVR008p) General Posters

Program Area: ENVR: Division of Environmental Chemistry

Symposium Title: (ENVR009) Environmental Chemistry Sci-Mix Session

INSTITUTIONS

1. PID Analyzers, LLC, Sandwich, Massachusetts, US, 02563, United States

2. Old Dominion University, Norfolk, VA, United States

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Jennifer Maclachlan, Jack Driscoll, Greg and Carey Cutter

AUTHORS

1. Jack N. Driscoll¹ , PID Analyzers, LLC, 2 Washington Circle, #4, Sandwich, Massachusetts, US, 02563, United States , 6176994307, United States, pidguy@aol.com

2. Jennifer L Maclachlan¹ , PID Analyzers, LLC, 2 Washington Circle, #4, Sandwich, Massachusetts, US, 02563, United States , 6176994307, United States, pidgirl@gmail.com

3. Gregory Cutter² , Old Dominion University, Dept of Ocean, Earth and Atmospheric Sciences, 5115 Hampton Boulevard, Norfolk, VA, 23529, United States , 757-683-4929, gcutter@odu.edu

4. James Maclachlan, PID Analyzers, LLC, 2 Washington Circle, #4, Sandwich, Massachusetts, US, 02563, United States , 6176994307, United States, sales@hnu.com

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Title: Photoionization (PID) and GC-PID method for the measurement of arsenic in food and juice  

Abstract Body: Numerous methods have been described in the literature for the determination of arsenic both in water and in particulate matrices. Many of these methods essentially employ the same principles, but apply different reagents, concentrations or instrumentation. The most popular techniques for arsenic analyses include hydride generation and AA, ICP-OES or ICP-MS. Although many water labs have these types of spectrometers already, many labs do not. The cost of these types of spectrometers is in the $100-200K price range.

Many labs would have to choose the older colorimetric methods but we have developed and modified the PID and GC-PID methods for arsenic in water analysis at ppb levels (1) to work with food and juice. The system cost is a fraction of the $100K spectrometer price.

Photoionization (2) & GC-PID (3) have been used to measure low ppb levels of As (3), As (5), total arsenic and organo arsenic compounds (GC-PID) in water. The latter method by Cutter (2) is one of the most sensitive methods available for arsenic in water with a detection limit of 0.075 ug/L and the ability to separate arsine, organoarsenic compounds and other organo metallic hydrides.

We will describe the modifications of the new method for arsenic in food and juice as well as the interferences, accuracy and precision for those samples.

1. Driscoll, JN and GA Cutter, “Total and Speciated Arsenic Compounds in Water by Photoionization and Gas Chromatography/PID”in "Toxic Trace Metal Remobilization & Remediation - A Geochemical Body of Work" to be published by the ACS (2012)
2. Driscoll JN, D. Lewis, R. Keip, J . Ann, H. Hu, , , DETERMINATION OF ARSENIC IN WATER AT LOW PPB LEVELS,Pittsburgh Conference on Anal. Chem…, Paper # 2350-7, March 2006
3. Cutter, G.A. and L.S. Cutter.. The biogeochemistry of arsenic and antimony in the North Pacific Ocean. Geochem. Geophys. Geosystems (G³), 7, Q05M08, doi:10,1159, 2006

Check out @pidgirl's *Arsenic* Board on Pinterest here

#PITTCON: ENVR Analysis: Pharmaceutical & Biologically Active Materials

#pittcon Environmental Analysis: Pharmaceutical and Biologically Active Materials Thursday, March 15th, 2012 2:00 PM Room: 311C Speakers: 2:00 PM Optimization and Application of Solid Phase Microextraction (SPME/LC/MS/MS) for Determination of Pharmaceuticals in Urban Wastewater Effluent, Paul Togunde 2:20 PM Fast Ultra High Performance Liquid Chromatographic Method for the Simultaneous Determination of Some Selected Emerging Contaminants in Environmental Water Samples Using Superficially-Porous Fused Core Particles as an Alternative to Sub 2 µm Particles, Heba Shaaban 2:40 PM Identification of Oxidation By Products of Selected Pharmaceutical and Personal Care Products in Drinking Water Treatments, Qihua Wu 3:00 PM Analysis of ß-blockers and ß2-agonists in Distilled and Waste Waters Using Liquid Chromatography–Tandem Mass Spectrometry in Conjunction with Solid-Phase Extraction, Alaa Salem 3:20 PM Recess 3:35 PM Speciation Analysis of Gadolinium Chelates in Hospital Effluents and Wastewater Treatment Plant Sewage, Uwe Karst 3:55 PM Rapid Separations on a Portable GC with Resistively Heated Columns, Jack Driscoll 4:15 PM Sensitized Chemiluminescence System Based on Hydrogen Peroxide and Fenton Reagent, Mohit Patel 4:35 PM Quantitative Improvement of the POCIS (Polar Organic Chemical Integrative Sampler) for Pharmaceutical and Pesticide Compounds, Helene Budzinski