Separation of mercury from VOC’s and selective detection using gold film amalgamation and photoionization detection
Accepted for presentation at #ACSDenver 2015 on March 23, 2015: PAPER ID : 2152487 PAPER TITLE: “Separation of mercury from VOC’s and selective detection using gold film amalgamation and photoionization detection” DIVISION: [ANYL] Division of Analytical Chemistry SYMPOSIUM : Advances in Analytical Separations PRESENTATION FORMAT : Oral Authors: J.N. Driscoll and J.L.Maclachlan, PID Analyzers, LLC Sandwich, MA USA We used a sensitive but nonspecific photoionization detector (PID) with a 10.6 eV lamp to measure mercury that has an ionization potential of 10.43 eV. The PID responds to both mercury and VOC’s and the VOC’s have to be removed to make the technique specific for mercury. The chemistry of the gold/mercury amalgam makes this method specific for mercury and eliminates interference from VOC’s. This technique also concentrates the sample making the method sensitive to sub ppb levels. Mercury permeation tubes were used to generate levels from 0.02 to 1